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There is more to this than just the passage I have here, from an article by Peter lindemann. Please, if you are making your own colloidal silver you must read this article to get a better view on the process and reasons behind it.

Pat

The very best voltage for the reaction is 30 volts, because the electrodes run the cleanest at this voltage. If you have a small power supply, set it for 30 volts. If you are running on batteries, it is best to start at 36 volts (three 12 volt batteries or four 9 volt batteries) and let the batteries drain down from there. Holding the silver electrodes at a uniform distance away from each other yields a better product. When 30 volts is applied across silver electrodes held uniformly apart in distilled water, a totally different event happens. First, the reaction proceeds very slowly. Often, for the first 15 minutes nothing seems to be happening. Then finally, a faint yellow mist will begin to form. Within a few minutes, the reaction will speed up, but the particles produced will be a golden- yellow as viewed with a flashlight.

Using this method, 8 ounces of distilled water at room temperature can be made into a 3-5 ppm colloidal silver preparation in 20-25 minutes. Made this way, colloidal silver can cost under 10 cents/oz to make. Electron microscope photographs of this product show a silver particle size in the range .001 to .004 microns. During manufacturing, the particle cloud is a golden-yellow. These particles will hang in the water at the level they are produced, and for the most part, will not fall to the bottom of the glass. This is what a "colloidal" preparation of silver looks like. After the particles disperse, the water will look clear again, but may turn a light yellow if the concentration is high enough and after the particles have become evenly dispersed.

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